Abstract

The novel nido 11-vertex nickelaborane [{μ-3,7(PhCOS)}-{μ-7,8-(PhCOS)}-{μ-7,11-(PhCOS)}-10-PPh 3 nido-7-NiB 10H 7] ( 1) was synthesized and characterized by X-ray diffraction analysis. This the first metallaborane cluster that has three rings of exo-polyhedral cyclization.

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