Abstract
First tetrahydrofuran-2,3,4,5-tetracarboxylic acid-bridged manganese(II) coordination polymer [Mn2L]n(L = tetrahy- drofuran-2,3,4,5-tetracarboxylic acid tetraanion) has been synthesized and characterized structurally. It crystallizes in the monoclinic space group P21/c. a = 14.9418(15)Å, b = 7.7340(8) Å, c = 10.7222(11) Å, β = 102.59(10)•. Both of the Mn (II) ions in the complex are six-coordinated with a distorted octahedral geometry, but the coordination environments for them are different. For every ligand, all of the oxygen atoms are participating in coordinating. The complex displays a two-dimensional polymer through coordination bonds.
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