Abstract
The electron-donating and electron-accepting properties of N-heterocyclic carbene (NHC) ligands play a pivotal role in governing their interactions with transition metals, thereby influencing the selectivity and reactivity in catalytic processes. Herein, we report the synthesis of Pd/NHCF and Ni/NHCF complexes, wherein the electronic parameters of the NHC ligands were systematically varied. By performing a series of controlled structure modifications, we elucidated the influence of the σ-donor and π-acceptor properties of NHC ligands on interactions with the transition metals Pd and Ni and, consequently, the catalytic behavior of Pd and Ni complexes. The present study deepens our understanding of NHC-metal interactions and provides novel information for the rational design of efficient catalysts for organic synthesis.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
