Abstract

Two chiral crown ethers (+)-(S)-(4) and (–)-(R,R)-(5) with a 4,4′-biphenanthryl moiety as the chiral centre have been prepared, and their chiral recognition properties were examined to show that (+)-(S)-(4) has a high enantiomer selectivity for 2-aminotetralin and 1,2-diphenylethylamine.

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