Abstract
A series of new copper(II) ternary complexes with N-(benzoyl)leucinate and N-(acetyl)phenylglycinate and certain N-heterocyclic ligands (quinoxaline, 2,4,6-tris-(2-pyridyl)-1,3,5-triazine and oxalic acid diimidazolide) have been synthesized and characterized by elemental analysis, IR and EPR spectra as well as thermogravimetric analysis. The structure of bis-(N-(acetyl)phenyl-glycinato)-bis-(imidazole)copper(II) was also characterized by X-ray single crystal analysis. The structure consists of monomeric units, in which the copper atom exists in a square-planar geometry with a CuN2O2 chromophore with two centrosymmetrically related carboxyl oxygens and imidazole nitrogen atoms.
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