Abstract
AbstractA novel monoanionic CNC‐type pincer ligand featuring a pyrrolide as a central donor and imidazo[1,5‐a]pyridin‐3‐ylidenes as arm donors is designed and synthesized. The reaction of the lithium complex prepared from the pincer ligand with [RhCl(CO)2]2 gave the corresponding rhodium(I) carbonyl complex. X‐ray analysis and IR spectroscopy of the rhodium complex indicate that the newly designed and synthesized pincer ligand has an electron‐withdrawing character with a planar backbone.
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