Abstract

Abstract In this paper we report on heterojunction between the hole transporting polymerpoly (3, 4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT: PSS) and zinc oxide (ZnO) nanowires grown on an indium tin oxide (ITO) coated polyethylene terephthalate (PET) plastic substrate. For the fabrication of heterojunction simple and low cost solution methods are used. The deposited films and heterojunction are characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), photoluminescence (PL) and electroluminescence (EL) measurements. Electroluminescent and photoluminescent spectra of the hybrid heterojunction show one ultraviolet (UV) near-band-edge emission peak. The current-voltage characteristic confirms the junction formation between the polymer and ZnO nanowires and shows good rectifying p-n junction diode type behaviour of the fabricated structure. The charge transfer process in heterojunctionis explained by band energy diagram.

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