Synthesis and characterization of linear/nonlinear optical properties of graphene oxide and reduced graphene oxide-based zinc oxide nanocomposite

Abstract

In this paper, we aimed to investigate the linear and nonlinear optical properties of GO-ZnO and RGO-ZnO nanocomposites in comparison with pure GO and reduced graphene oxide (RGO). For this purpose, GO, RGO, GO-ZnO, and RGO-ZnO were synthesized and characterized by Fourier transform infrared (FT-IR), Ultraviolet–Visible (UV–Vis) absorption, X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX). XRD and EDX analysis indicated the reduction of GO as well as the successful synthesis of GO-ZnO and RGO-ZnO nanocomposites. The FT-IR spectroscopy showed that absorption bands were at 3340 cm−1, 1630 cm−1, 1730 cm−1 and 480 cm−1 related to OH, C=C, C=O, and Zn–O stretching vibrations, respectively. The direct band gaps of GO, RGO, GO-ZnO and RGO-ZnO from UV–Vis spectra were at 3.36, 3.18, 3.63 and 3.25 eV, sequentially. Moreover, the third-order nonlinear optical properties were investigated using a z-scan technique with Nd: YAG laser (532 nm, 70 mW). It can be seen that the nonlinear absorption coefficient value (upbeta ) increased from 5.3 × 10–4 (GO) to 8.4 × 10–3 cm/W (RGO-ZnO). In addition, nonlinear refractive index (n2) of the GO, RGO, GO-ZnO, and RGO-ZnO was obtained as 10.9 × 10–10, 14.3 × 10–10, 22.9 × 10–10, and 31.9 × 10–10 cm2/W respectively.