Abstract
Twelve new complexes of lanthanide nitrates with 1,4,7,10,13-pentaazacyclopentadecane (L) have been prepared under nitrogen using anhydrous acetonitrile as reaction medium. The complexes having the composition M(L)(NO 3) 3 (M = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er, Tm, Yb and Y) were characterized by elemental analysis, IR spectra and conductivity measurements. An X-ray crystallographic structural determination of the lanthanum complex shows that the five nitrogen atoms from the ligand coordinate to the metal ion on one side and the three bidentate nitrate groups coordinate on the opposite side. The coordination number of the metal ion is eleven.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
