Abstract
Reaction of trimethylgallium (trimethylindium) and triethylgallium (triethylindium) with N-salicylidene 2-aminopyridine or N-salicylidene 2-methoxyaniline in benzene solution yields seven intramolecular coordinated Group 13 metal Schiff-base complexes. All complexes obtained were characterized by elemental analysis, 1H-NMR, IR and mass spectrometry. The structure of dimethyl[ N-salicylidene 2-aminopyridine]gallium ( 1) was determined by X-ray single crystal analysis. The Ga atom is four coordinate in the structure. Photoluminescent emission spectra of complexes dimethyl[ N-salicylidene 2-aminopyridine]gallium ( 1), diethyl[ N-salicylidene 2-aminopyridine]gallium ( 3), diethyl[ N-salicylidene 2-aminopyridine]indium ( 4) and dimethyl[ N-salicylidene 2-methoxylaniline]gallium ( 5) were measured. The maximum emission wavelength is between 503 and 511 nm, respectively on radiation by UV light.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
