Abstract
In the current research we tried to isolate unsymmetrical Schiff base bearing bis-aryl tellurium dichloride by the treatment of 1-(thiophen-2-yl)-N-(p-tolyl)methanimine with anisyltellurium trichloride in carbon tetrachloride solvent at 80ºC. However, we are unable to isolate our desired compounds due to decomposition takes place along with tellurium separation. From the reaction mixture, we are able to isolate only yellow coloured needle shaped crystal of bis-(pmethoxyphenyl)tellurium dichloride: (p-MeOC6H4)2TeCl2 . The crystal was characterized by several spectroscopic techniques along with single crystal x-ray studies. The crystal are triclinic with a = 10.1853(12), b = 12.3771(16), c = 13.4842(17) Å, = 109.235(5)°,= 99.519(5)°, = 102.705(5)°, Z = 4 and the space group is P-1. The structure has been determined by single crystal x-ray studies at 100(2) K and the final R value calculated from 11485 reflectionswas 0.0497.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
