Abstract

Rapid treatment of uranium in seawater is an important topic that needs to be addressed urgently. Microgel materials are considered ideal for rapid adsorption due to their ability to absorb water quickly. In a seawater environment, amidoxime materials exhibit superior selectivity for uranium enrichment. However, the modification of amidoxime groups onto microgels must be conducted in organic solvents. These solvents are unable to sufficiently swell and dissolve common microgels, leading to shrinkage that nearly blocks all modification reactions. Here, the thermo-responsive N'N-diethylpropionamide (DEA) was chose as the skeleton monomer to synthesize microgels, which showed both good hydrophilicity and oleophilicity properties The difference between the particle size of synthesized microgels in water and ethanol was not obvious. Due to the integration of microgels and kairamidoxime materials, the AO-Microgels demonstrate a maximum adsorption capacity of 79.29% within just 3 min. Additionally, their selective adsorption capacity for uranium in simulated seawater is remarkable. Furthermore, it simplifies the recycling process because of its intelligent temperature responsiveness.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.