Syntheses, crystal structures and luminescent properties of two new Zn(II) coordination polymers based on a dicarboxylate and different imidazole-containing ligands

Abstract

To investigate the effect of different imidazole-containing ligands on the structure of coordination polymers, two new Zn(II) coordination polymers based on 1,4-cyclohexanedicarboxylic acid (H2cda) and two different imidazole-containing ligands, [Zn(cda)(bib)0.5]n (1) and [Zn(cda)(bmib)0.5]n (2) (bib = 1,4-bis(imidazol-1-yl)benzene and bmib = 1,4-bis(2-methylimidazol-3-ium-yl)benzene), have been synthesized and characterized by single-crystal X-ray diffraction. Complex 1 shows a 3-D structure with point symbol (4.82.103).(4.82). Complex 2 displays a 2-D layer structure with an –AB– stacking sequence.