Abstract
Two novel cyano CuII–AuI bimetallic complexes, Cu(cyclen)[Au(CN)2]21 (cyclen = 1,4,7,10-tetraazacyclododecane) and Cu(pyz)[Au(CN)2]22 (pyz = pyrazine) were prepared; 1 has a dimeric structure arising from AuI⋯AuI interactions, while 2 consists of linear pyrazine-bridged copper chains intercalated to produce a 2-D pleated sheet structure.
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