Abstract
(2-Trimethylsiloxy)ethyl isocyanide reacts with Pd(CN) 2 and Pt(CN) 2 to give trans-[Pd(CN) 2( CN(H)CH 2CH 2O) 2 ] ( 1), trans-[Pt(CN) 2( CN(H)CH 2CH 2O) 2 ] ( 2) and cis-[Pt(CN) 2( CN(H)CH 2CH 2O) 2 ] ( 3), respectively. Complexes 1–3 have been characterized by crystal structure determinations. In the cis compound 3, the carbene ligands are linked by NH…O hydrogen bonds. A measured Pt…Pt distance of 3.2828(6) Å in this crystal structure indicates a weak Pt…Pt interaction.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
