Abstract
Perfluoroorgano copper compounds are formed by reacting bis(perfluoroorgano) cadmium complexes with copper(I) salts [1]. Some reactions with inorganic compounds are described. The reactivities and the limits to react of perfluoroorganylation reagents shall be discussed.Cd(CF3)2 complexes react with silver (I) salts to form [Ag(CF3)4]- as the final product [2]. Here we report the syntheses of AgRf and [Ag(Rf)2]-, which are indentified by n.m.r. spectroscopy. Some reactions of these perfluoroorgano silver(I) derivatives will be discussed.A new route to prepare AgC6F5 is presented.
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