Abstract
The reactions of 1,1,2,2-tetrafluoroethane-1,2-bisulfenyl-chloride 1 and symmetrical azines 2 yield the conjugated trans-diazenes 3 as deep-coloured solids. Unsymmetrical azines 4 react with 1 under elimination of hydrogen chloride to give 1,3-dithiolane-substituted azine derivatives as pale-coloured liquids. The crystal structure of 3b has been determined by single crystal X-ray diffraction. A participation of the phenyl group in the conjugated system is not observed in 3b.
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