Abstract
In this article, the synergetic effect between the B‐ and Al‐based acidic sites in B–Al co‐doped mesoporous MFI nanocrystals (denoted as m‐B‐Al‐S1) is rationally applied to modify the alcoholysis process of furfuryl alcohol. The porosity and dopant concentration of the m‐B‐Al‐S1 materials are optimized via a modified Kirkendall growth method to boost the ultra‐high selectivity to ethyl levulinate reactions (94%). The m‐B‐Al‐S1 catalyst also shows good stability for further reuses.
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