Abstract
In the present work, electrodeposited chromium coatings were strengthened with 3 mol% yttria-stabilised zirconia nanoparticles (YSZ) and carbon nanotubes (CNT) to analyse anti-corrosive and wear properties of the coatings. Highest hardness (~24 GPa), minimum scratch wear rate i.e. ~3 × 10−11 m3/Nm and highest corrosion resistance of ~3.9 kΩcm2 was obtained by synergistic incorporation of YSZ and CNT in Cr matrix. This can be linked to high dislocation density ~22 × 1011 cm−2 (Orowan effect) and compressive residual stresses i.e. ~840 MPa (Cr-YSZ-CNT), which tend to seal-up micro-holes and cavities, thereby, restricting the onset of wear and corrosion in the matrix. Addition of inert YSZ nanoparticles imparts chemical stability as well as hardness to the Cr matrix (~11 GPa for Cr-YSZ, ~8.4 GPa for Cr). Further, CNT incorporation, apart from matrix strengthening, results in low COF (~0.12) due to self-lubricating nature of CNTs, which leads to reduced wear rate of ~3.8 × 10−11 m3/Nm (Cr-CNT) with respect to Cr and Cr-YSZ. Thus, barrier protection and corrosion inhibition might be protective mechanisms for Cr-YSZ-CNT coating that make it suitable for engineering and industrial applications in order to protect the vital components exposed to tribological and corrosive media conditions.
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