Abstract

Liquid–liquid extraction of zirconium(IV) was investigated from dilute hydrochloric acid medium by salicyaldoxime (HA) in dichloromethane. The metal was spiked with 95 Zr and analyzed by its radioactivity. The effects of different donors, like trioctyl phosphine oxide (TOPO), triphenyl phosphine oxide (TPPO), tributyl phosphine oxide (TBPO), tributyl phosphate (TBP), trioctyl amine (TOA) and Amberlite LA-2 were studied. The adduct formation constants for both binary species (metal–ligand) and ternary species (metal–ligand–donor) were also calculated form the distribution data.

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