Abstract
Carbon monoxide has been excited with monochromatic synchrotron radiation in the 14–35 eV range using the Swedish synchrotron facility MAX in Lund. The decay products were studied in various detection channels such as formed CO+ and C+ ions using mass spectroscopy and visible or VUV fluorescence using photon detection. A rich line structure is observed which is attributed to CO Rydberg series converging to theX,A,B,D,C andE states in CO+. While a great number of these lines are already known, some of them are classified here for the first time. The combination of information from the fluorescence spectra and the mass spectra contribute important information concerning the autoionization and predissociation of these various Rydberg series.
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