Abstract
Nanoporous metallic glass Pd (PdNpore) was prepared by electrochemical dealloying of metallic glass Pd30Ni50P20 (eq. 1). PdNpore catalyzed the Suzuki-Miyaura coupling of boron reagents 1 with aryl halides in the presence of KOH to afford the corresponding biaryls in up to 99% yield (eq. 2, 15 examples).
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