Surface Wettability of Cellulose Sponges on Effective Oil Uptake.

Abstract

Designing absorbents having specific wettability toward both oil and water is the key for selective and effective oil absorption and removal. For this purpose, establishing explicit correlations between surface tension of oils and surface wettability of absorbent is crucial. In this study, we modified common low-cost cellulose sponges with various organosilanes to achieve a range of hydrophobicity/oleophilicity and then assessed their oil uptake selectivity and capability. Oil uptake was followed as mass uptake versus time and analyzed based on the spreading coefficient (S) of a liquid over a solid surface. The results showed that sponges needed to be hydrophobic, not necessarily superhydrophobic, to selectively absorb oil from an oil/water mixture. To achieve a fast uptake and a high uptake capacity, an S ≥ 0 was necessary, that is, when the sponges were completely wet by the oil. Increasing the porosity of cellulose sponge led to a slight increase in oil uptake capacity, and a greater increase resulted when bacterial cellulose sponges that consisted of smaller and more uniform voids/pores were used. S ≥ 0 could be used as a criterion for evaluating effective and rapid oil uptake for porous absorbents, especially for those containing heterogeneous pore structures, such as common cellulose sponges.