Abstract

Highly efficient organic light-emitting devices (OLEDs) have been realized by insertion of a thin insulating lithium fluoride (LiF) layer between aluminum (Al) cathode and an electron transport layer, tris-(8-hydroxyquinoline) aluminum (Alq 3). In this paper, we study the surface morphology of LiF on Alq 3 by synchrotron X-ray scattering and atomic force microscopy (AFM) as a function of thickness of LiF. We also study the interdiffusion of LiF into Al cathode as well as into Alq 3 layer as a function of temperature. Initially, LiF molecules are distributed randomly as clusters on the Alq 3 layer and then gradually form a layer as increasing LiF thickness. The interdiffusion of LiF into Al occurs more actively than into Alq 3 in annealing process. LiF on Alq 3 induces the ordering of Al to (1 1 1) direction strongly with increasing LiF thickness.

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