Abstract

The role of surface transport in the passage of a gas at low pressure through fine tubes or pores is examined in terms of simple models of mobile and localized adsorption. The amount of surface transport becomes about equal to the amount of gas transport when the tubes or pores have radii of the order of several hundred Angstrom units. The theory predicts that surface transport will have little effect on the pressure gradient across the tube or pores in the absence of a temperature gradient. But the pressure gradient should be increased considerably, as a result of surface transport, over the usual (thermal transpiration) pressure gradient when there is a temperature gradient across the tube or pores.

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