Abstract

Abstract Single crystals of 2-furichydrazinium picrate monohydrate (FHM) grown from ethanol at room temperature belong to the space group P21/c as elucidated from X-ray analysis. Supramolecular assembly is constructed by weak C-H…O, N-H…O and π-π stacking interactions. Intermolecular interactions are analysed by Hirshfeld surface. It exhibits optical limiting property and third-order nonlinear optical character as revealed by Z-scan studies. Band gap energy was estimated by Kubelka-Munk algorithm. Molecular interactions were quantified by Hirshfeld surface analysis and supported well the experimental results.

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