Supercritical phase fischer‐tropsch synthesis: Catalyst pore‐size effect

Abstract

AbstractThe Fischer‐Tropsch synthesis reaction was conducted in a supercritical fluid medium using a fixed‐bed reactor. Tailor‐made catalyst supports which had sharp pore diameter distributions were prepared by the pH swing method. The relationships between the catalyst pore structure and the catalytic activity or the product distribution were studied. The influence of the catalyst pore size on the mass transfer of reactants and products was also characterized. The catalyst pore size affected not only catalytic activity but also product selectivity. The diffusion of reactants inside the catalyst pellets in the supercritical fluid media was simulated and the effects of catalyst pore size and catalyst particle size on catalytic performances were consistent with simulation results.