Sunlight-pumped two-dimensional thermalized photon gas

Abstract

The Liouville theorem states that the phase-space volume of an ensemble in a closed system remains constant. While gases of material particles can efficiently be cooled by sympathetic or laser cooling techniques, allowing for large phase-space compression upon suitable coupling to the environment, for light both the absence of an internal structure, as well as the nonconservation of photons upon contact with matter imposes fundamental limits for three-dimensional light-harvesting systems, such as fluorescence-based light concentrators. An advantageous physical situation can in principle be expected for dye-solution-filled microcavities with a mirror spacing in the wavelength range, where low-dimensional photon gases with nonvanishing and tunable chemical potential have been experimentally realized. Motivated by the goal to observe phase-space compression of sunlight by cooling the captured radiation to room temperature, in this work we theoretically show that in a lossless, harmonically confined system the phase-space volume scales as ${(\mathrm{\ensuremath{\Delta}}x\mathrm{\ensuremath{\Delta}}p/T)}^{d}=\mathrm{constant}$, where $\mathrm{\ensuremath{\Delta}}x$ and $\mathrm{\ensuremath{\Delta}}p$ denote the position and momentum spread and $d$ the dimensionality of the system ($d=1$ or 2). Experimentally, we realize a corresponding sunlight-pumped dye microcavity and demonstrate thermalization of scattered sunlight to a two-dimensional room temperature photon gas with nonvanishing chemical potential. Prospects of phase-space buildup of light by cooling, as can be feasible in systems with a two- or three-dimensional band gap, range from quantum state preparation in tailored potentials up to technical applications for more efficient collection of diffuse sunlight.