Abstract
The subsolidus phase relationships of the system ZnO–Li 2O–WO 3 have been investigated by X-ray diffraction (XRD) analyses. There are one ternary compound, five binary compounds and eight 3-phase regions in this system. The new ternary compound Li 2Zn 2W 2O 9 was found by the powder diffraction pattern. The corresponding crystal structure of this compound was refined by Rietveld profile fitting method. It belongs to a trigonal system with space group P 3 ¯ c 1 and lattice constants are a = 5.1438(2) Å, c = 14.1052(3) Å, and its thermal property was studied.
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