Abstract
Subsolidus phase relations in the system Ba0‐Ti02‐Ge02 were investigated using conventional solid‐state reaction techniques and X‐ray powder diffraction. The existence of 2 ternary compounds, BaTiGe309 and BazTiGeZ08, was confirmed and their X‐ray crystallographic data are presented. The compound BaTiGe309 has a lower limit of stability at 1135°C and melts incongruently at 1232°C; Ba2TiGe2O2 melts congruently at 1228°C. Subsolidus compatibility relations in the ternary system were established and tie lines between the various phases which constitute a total of 12 compatibility triangles at 1000°C are shown in a subsolidus phase diagram.
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