Study on the nematicidal activity and chemical structure of NO bidentate Schiff base some metal complexes

Abstract

AbstractA series of Co(II), Cu(II), Y(III), Zr(IV), La(III), and U(VI) complexes derived from 2‐(2‐hydroxybenzylidinemine)‐benzoic acid (L) ligand were synthesized. The mode of bonding of L and the structure of its metal complexes were investigated using different analytical and spectral tools (FT‐IR, UV–Vis, 1H NMR, mass, and XRD). The ligand chelated with the metal ions as a neutral bidentate through oxygen and azomethine nitrogen atoms. All metal complexes adopted octahedral geometry with characteristic color for metal ions. The results of magnetic moment measurements supported paramagnetic for some complexes (Co(II) and Cu(II)) and diamagnetic phenomena for the other complexes. The thermal decomposition of the ligand along with its metal complexes was explained. The molar conductance values of all complexes in (DMF) were found in the range 154.50 to 250.20 S cm2 mol−1 at room temperature. The activation thermodynamic parameters, such as E*, ΔH*, ΔS* and ΔG*, were calculated from the DTG curves using Coats–Redfern (CR) and Horowitz–Metzeger (HM) methods at n = 1 or n ≠ 1. The nematicidal activity of the synthesized L and their metal complexes was screened.