Abstract
The crosslinked polymer of P(MMA-MAh)-PEG1500 was synthesized by reacting polyethylene glycol (PEG1500) with the copolymer of poly(methyl metacrylate-maleic anhydride) (P(MMA-MAh)) and endcapping the residual carboxylic acid with methanol. The properties of gel polymer electrolyte (GPE), consisted of P(MMA-MAh)-PEG1500 used as polymer matrix, propylene carbonate (PC) as a plasticizer and LiClO4 as lithium ion producer, was undoubtedly depended on the micro interaction existed in the compo- nents. Characterization of interaction of the polar group (C=O and C—O—C) in PC or crosslinked polymer with Li + has been thoroughly examined using FTIR. The quantitative analysis of FTIR showed that the ab- sorptivity coefficient (a) of PC/LiClO4 and polymer/LiClO4 was 0.113 and 0.267, respectively, which meant
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