Abstract

ABSTRACT In this study, we attempted to examine the properties of La-substituted bismuth titanate (BLT) thin film utilizing piezoresponse force microscope (PFM). BLT thin films were made using two step rapid thermal annealing (RTA). Three BLT thin films with random crystallographic orientation were obtained by varying the RTA conditions. AFM images show that the BLT thin film consists of three distinct shapes of grains. Each grain revealed different piezoresponse according to their shapes. Therefore, we investigated the relationship between the shape of a grain and polarization orientation. In addition, we studied grain polarization by monitoring the difference between the initial PFM image and PFM image after poling using 3D PFM. It is very useful to understand the piezoresponse in terms of polarization. Furthermore, it provides information about the domain motion in the BLT thin film with random crystallographic orientation.

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