Abstract
The application of matrix isolation infrared and Raman spectroscopy to the study of the self-association of hydrogen bonding substances is discussed. The use of the technique to elucidate the structures of small multiner species of hydrogen chloride, hydrogen cyanide, water and ammonia is described. The results of far infrared spectral studies enable some of the hydrogen bond stretching and bending modes of these species to be identified. Matrix spectra of the pyridine-hydrogen chloride complex are also discussed.
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