Abstract
The calculations carried out in Part II (F. Mas, J. Puy, F. Sanz and J. Virgili, J. Electroanal. Chem., 183 (1985) 41) to obtain the current-time curves in pulse polarography when both reactant and product follow a Langmuir isotherm are applied to the case of normal pulse polarography (NPP). The morphology of the exact polarographic curves is analyzed with respect to the adsorption parameters and the accuracy of the approximate curves is discussed. A special comment is made about the limiting current and its dependence on the adsorption parameters. Finally, a method of obtaining the adsorption parameters from the approximate equations is outlined.
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