Abstract
Batch equilibration studies have been carried out to understand the uptake of Th(IV), U(VI) and Pu(IV) on a conventional gel type cation exchange resin, Dowex 50WX8, from TBP-Shell Sol-T mixtures containing different amounts of nitric acid. Based on the results of the equilibration studies, column experiments have been carried out and conditions optimized to achieve separation of these elements present in binary and ternary mixtures. The influence of water content of the resin phase and the nature of the exchanging cation on the extent of uptake has also been investigated.
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