Abstract

The chiral epoxy alcohol (1, 2R)-epoxy-3S-tridecanol (3) was synthesized in 92% e. e. according to kinetic resolution of (±) 1-tridecen-3-ol (2) by Sharpless asymmetric epoxidation. 3 was then transformed to (7R, 8S)-la, the sex pheromone of gypsy moth, in overall yield of 60% in 5 steps.

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