Abstract
Possibilities of studying distribution potentials (Galvani potentials) of salts and their ionic components for the water-nitrobenzene and water-1,2-dichloroethane interfaces are presented. The proposed method takes advantage of cells with transport in which a distribution system containing tetraethylammonium picrate serves as the reference interface, the Galvani potential of such a system being close to zero. The measurements carried out for several electrolytes containing one hydrophobic and one hydrophilic ion have shown a satisfactory agreement with the potential values calculated from the literature data on extraction for the water-nitrobenzene system, assuming that the energies of transfer of the tetraphenylarsonium and tetraphenylborate ions are equal.
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