Abstract
This report compares experimental data for the overpotential dependence of the stationary nucleation rate I st and of the induction time t o obtained in two different ways: (i) by varying the potential E n of the working electrode at a constant concentration of metal ions (standard pulse potentiostatic technique), and (ii) by varying the concentration of metal ions at a constant electrode potential E n (modified pulse potentiostatic technique). It is shown that the latter experimental method allows us to fix the surface state of the working electrode and to create well-defined conditions for nucleus formation. Information is obtained on the rate-determining step of the nucleation process.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
