Studies of consecutive reactions of quinones in a reversed geometry mass spectrometer

Abstract

AbstractConsecutive reactions involving the ejection of molecules of carbon monoxide from quinone systems have been studied. Using a reversed geometry double focusing mass spectrometer, the individual steps of a consecutive reaction may be separated into different field free regions. The structure of ions formed in the ion source may be compared with those formed from the fragmentation of metastable ions in a field free region by studying differences in the pattern of translational energies released when they break. In the case of anthraquinone it is found that two structures exist for the [MCO]+˙ ion. Critical energy measurements strengthen this argument. Furthermore, 18O labelling has been used to distinguish between the loss of carbon monoxide from different positions on the molecular ion of 1‐hydroxyanthraquinone.