Abstract
Di-μ-hydroxo-bis(dibutylperchloratotin), [Sn(ClO 4 )(OH)(C 4 H 9 ) 2 ], M r =349.38, monoclinic, P2 1 /c, a=11.749 (3), b=8.300 2), c=14.725 (2) A, β=103.97 (2) o , V=1393 (1) A 3 , Z=4, D x =1.665 g cm -3 , λ(Mo Kα)=0.71069 A, μ=20.3 cm -1 , F(000)=696, T=153 K, R=0.032 for 1568 reflections. Dibutylhydroxystannyl perchlorate exists as a dimer [Bu 2 (OH)SnClO 4 ] 2 consisting of a four-membered ring with alternating Sn and O atoms. The ring O atoms are protonated and the Sn atoms are the centers of very distorted trigonal bipyramids. The apical positions of each bipyramid are occupied by a perchlorato group with a very long Sn-O bond length and the ring O atom with a longer Sn-O bond distance
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