Abstract

AbstractThin Na1−xKxI: TI+ mixed crystals with about 1 μm thickness have been prepared from melt, and the A band of TI+ on the absorption spectra has been observed in the temperature range 11 to 300 K. A distinct splitting of the band is recognized in the composition range of 0.1 < × < 0.6 at low temperatures though it does not occur in NaI: TI+ (x = 0) and KI: TI+ (x = 1). The low‐energy component of the band shifts continuously with x similarly as the peak of the exciton bands. On the basis of the temperature dependence, the structure is attributed to the static perturbation in addition to the dynamical Jahn‐Teller effect.

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