Abstract
Mixed CH(4)/CF(4) clusters as well as pure clusters of CF(4) were produced by adiabatic expansion and studied by carbon 1s (C1s) X-ray photoelectron spectroscopy. Evidence is presented that CH(4) and CF(4) do indeed form binary clusters in CH(4)/CF(4) coexpansion experiments and that these clusters exhibit radial structure; i.e., CF(4) is primarily found in the bulk. The interpretation of the photoelectron spectra is supported by calculations of C1s ionization energies based on theoretical clusters models.
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