Abstract
ln the title compound, 3,6,9,12,15-pentaoxabicyclo- [15.3.1]henicosa-1(21),17,19-triene-ammonium bis(1,2-benzenediolato)borate (1/1), the ammonium cation is hydrogen bonded by three of its H atoms to the crown ether, and by the remaining H atom to the O atom of the catecholborate anion. Thus the crown ether competes favourably with the catechol ligands for hydrogen bonding with the ammonium cation
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