Abstract
Dehydrosesquicineole (1), a sesquiterpene ether recently isolated from Artemisia sieberi, was synthesized starting from the bicyclic ketone 2a by a Bamford-Stevens reaction via the hydrazone 2b. Catalytic hydrogenation of 1 gave selectively either sesquicineole (3,7-epoxybisabol-10-ene, 3) or dihydrosesquicineole (4). The odour strength decreases from 1 to 3 to 4; the odour quality with fruity and floral tonalities is similar
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