Abstract
Borate ester formation of carbohydrate oximes and related compounds, including acetohydroxamic acid, has been studied using 11B and 13C NMR spectroscopy. It is shown that the oxime hydroxyl is involved in the borate ester formation. The resulting six-membered ring borate monoesters are more stable than the five-membered ring erythro- or threo-borate monoesters involving a vicinal diol function.
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Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
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