Abstract

A neutron-diffraction study of TlH 2PO 4 at room temperature (RT) is presented as part of an investigation of the group of monoclinic dihydrogen phosphates: NaDP, deuterated-KDP, CsDP, and TlDP (DP denotes H 2PO 4). The structure of TlDP, and the nature of its phase transition at 230 K, are discussed and compared with paraelectric CsDP — with which TlDP is nearly isomorphous at RT.

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