Structural Changes in Wormlike Micelles on the Incorporation of Small Photoswitchable Molecules.

Abstract

Chromophores susceptible to light-induced trans-cis isomerization embedded in cylindrical micelles can modify micelles and their light-responsive performance. A small chromophore (4-(phenylazo)benzoate ion) is embedded in cylindrical micelles made of cetyltrimethylammonium bromide (CTAB) and sodium salicylate (NaSal) in water. The microstructure is examined by scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR). Rheological behavior and the length scales of the micellar network are determined by rheology and microrheology. The chromophore substantially modifies the micelles even without UV irradiation. The larger is the chromophore concentration, the smaller is the micellar length. Additional length scales of the micellar network do not substantially vary even when NaCl is added. Chromophore incorporation also modifies the rheology of the micellar solution, although gradient shear banding is preserved. Viscosity decreases as the chromophore concentration increases, and viscoelastic spectra are modified, but when they are correctly rescaled, they can be superimposed. The addition of the chromophore makes the fluids more Maxwellian, particularly when NaCl is also added. When the chromophore is incorporated into the micelles, there is a response after UV irradiation, although it does not produce a significant rheological change.