Strong photo-thermal coupling effect boosts CO2 reduction into CH4 in a concentrated solar reactor

Abstract

This study is dedicated to solving the problems of low energy utilization and low yield in the conventional photocatalytic CO2 reduction process. Herein, we constructed a novel concentrated solar (light) reactor and enabled the titanium foam-based monolithic photocatalyst TF@TNT/0.4CoOx-0.1CuO to improve the solar energy utilization efficiency and CO2 conversion rate by concentrating light and its thermal effect. We found that the yield of CH4 increased up to 220 times (from 0.53 µmol/cm2 to 116.4 µmol/cm2) when the light intensity of the reactor was increased from 400 mW/cm2 to 4266 mW/cm2 (10.6 times). Meanwhile, the solar-to-fuel conversion efficiency was improved up to 0.35% in the concentrated solar (light) reactor. We further investigated the origin of the photothermal coupling effect with concentrated light through the electrochemical and photochemical measurements. It shows that the concentrated light can further lower the reaction barrier (from 41.62 to 31.51 kJ/mol) and the induced photothermal coupling effect could significantly increase the yield. This provides a valuable strategy for the efficient and environmentally friendly utilization of CO2 using solar energy.