Abstract
AbstractReaction of the ligand meso‐H2L, derived from cis‐diaminocyclohexane and ethyl cyano(ethoxymethylene)acetate, with nickel(II) acetate gives meso‐NiL. Spectrophotometric titration of RR‐NiL and meso‐NiL with various nitrogen bases reveals a strong influence of the steric hindrance of the diaminocyclohexanediyl bridge in meso‐NiL on the base adduct stability. The structures of RR‐NiL and meso‐NIL have been established by X‐ray diffraction.
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